authorisation ends within 12 months: 2026-12-31
Frisin
Authorisation number: 024511-00
- Formulation
- Gas packed in pressure bottle/tank
- first authorised
- 2016-10-10
- authorised until
- 2026-12-31
- Field of activity
- Insecticide
- Hazard to bees
- B3 – not hazardous to bees given the prescribed use
- Trial designation
- SER-78801-I-0-GA
Active substances
| Active substance | English name | Content | Basis | Type of substance | EU approved |
|---|---|---|---|---|---|
| Phosphan (Phosphorwasserstoff) | phosphane | 20.6 g/kg | parent structure | Wirkstoff | yes |
The chemical group (such as guanidines) is not provided by the BVL interface and therefore cannot be shown.
Modes of action
| Code | Mode of action | Text |
|---|---|---|
| WMI24A | – | Mode of Action (IRAC-Group): 24A |
The BVL records the mode of action as a WM-series condition; the group follows the FRAC, HRAC or IRAC classification.
Holder and distribution
- Authorisation holder
- S&A Service und Anwendungstechnik GmbH (DE)
Authorised uses (8)
| Crop | Pest | Area of use | Hazard to bees | Use no. |
|---|---|---|---|---|
| coffee | Insects | In piles of sacks under gas-tight canvas or in sufficiently gas-tight rooms | – | 024511-00/00-001 |
| cocoa | Insects | In piles of sacks under gas-tight canvas or in sufficiently gas-tight rooms | – | 024511-00/00-002 |
| oily seeds | Insects | In piles of sacks under gas-tight canvas or in sufficiently gas-tight rooms | – | 024511-00/00-003 |
| dried fruit | Insects | In piles of sacks under gas-tight canvas or in sufficiently gas-tight rooms | – | 024511-00/00-004 |
| stored cereals | Insects | Shallow storage | – | 024511-00/00-005 |
| stored cereals | Insects | Gas-tight silo unit with circulatory fumigation | – | 024511-00/00-006 |
| stored cereals | Insects | In piles of sacks under gas-tight canvas or in sufficiently gas-tight rooms | – | 024511-00/00-007 |
| stored cereals | Insects | Container (for consignments of goods) | – | 024511-00/00-008 |
Conditions of use
| Code | Text | Crop | Buffer zone |
|---|---|---|---|
| NW467 | The product and its remains, empty containers and packaging and rinsing fluids must not be dumped in water. This also applies to indirect entry via the urban or agrarian drainage system and to rain-water and sewage canals. | – | – |
Restrictions
| Code | Text | Crop | Buffer zone |
|---|---|---|---|
| SB001 | Avoid any unnecessary contact with the product. Misuse can lead to health damage. | – | – |
| NW264 | The product is toxic for fish and aquatic invertebrates. | – | – |
| NW262 | The product is toxic for algae. | – | – |
| WH952 | The indication identifying the mode of action must be assigned directly to each corresponding name of the active substance as supplementary information on the packaging and in the instructions for use. | – | – |
| WMI24A | Mode of Action (IRAC-Group): 24A | – | – |
| VS005-1 | Fumigations with substances stated in "GefStoffV" (Hazardous Substances Ordinance) annex I no.4.1 (1) till (3) require permission according to GefStoffV annex I no. 4.2 (1). When applying the product, the special regulations in GefStoffV annex I no. 4 in addition to the technical regulations for hazardous substances (TRGS 512 - Fumigations) must be observed. | – | – |
| VA5471 | Do not use in rooms with water-lines carrying drinking water except when fumigating goods covered with gas-tight sheeting in accordance with 'TRGS 512' (technical regulations for hazardous substances). | – | – |
| ST3312 | Wear respiratory equipment with filter (type/identification colour ...*)) for phosphane when applying/handling the product and suitable protective clothing according to TRGS 512. *) state respiratory equipment, gas filter type (identification letter and colour) and gas filter class. | – | – |
| SS2204 | Wear a protective suit for plant protection products and sturdy shoes (e.g. rubber boots) when applying/handling the product. | – | – |
| SS1201 | Wear standard protective gloves (plant protection) when handling/applying the product. | – | – |
| SF524 | Rooms/stores must be vacated and closed immediately after fumigation has been started. For use under gas-tight sheeting, put the goods in gas-tight packaging and vacate the danger zone immediately after fumigation has started. | – | – |
| SF514-1 | The operator or person equipped with adequate experience responsible for measuring the fumigation product used must check the ambient air regularly in accordance with 'TRGS' (technical regulation for dangerous substances) 512 (fumigations) until the area has been authorised for access to ensure that concentrations of the fumigation product which exceed the limit of detection (more than or equal to 0.01 ppm) do not occur outside of the specified danger zone. The measurement results and, if appropriate, the measures taken, must be documented and kept together with the fumigation documentation. | – | – |
| SE1201 | Wear tight fitting eye protection when applying/handling the product. | – | – |
| SB110 | The directive concerning requirements for personal protective gear in plant protection, "Personal protective gear for handling plant protection products" of the Federal Office of Consumer Protection and Food Safety must be observed. | – | – |
Notes
- Due to the manner in which authorisation governs application of the product, bees are not endangered.(B3)
- Due to the manner in which authorisation governs application of the product, populations of relevant beneficial organisms are not endangered.
Hazard classification (GHS/CLP)
Signal word
- Danger
Hazard pictograms
- GHS06
- GHS09
Hazard statements
- To avoid risks to human health and the environment, comply with the instructions for use.
- Causes skin irritation.
- Causes serious eye irritation.
- Fatal if inhaled.
- May cause respiratory irritation.
- Very toxic to aquatic life.
Precautionary statements
- If medical advice is needed, have product container or label at hand.
- Keep out of reach of children.
- Obtain special instructions before use.
- Do not breathe dust/fume/gas/mist/vapours/spray.
- Do no eat, drink or smoke when using this product.
- Wear protective gloves/protective clothing/eye protection/face protection.
- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- IF exposed or concerned: Immediately call a POISON CENTER or a doctor/physician.
- Store in a well-ventilated place. Keep container tightly closed.
- Store locked up.
- Dispose of contents/container to ...
Further information
Data source: PSM-API · Data as of: 2026-09-02
Only the authorisation notice together with the product label and instructions for use is legally binding.